Daguerreotype Object View

Support 
The support is composed of a sheet of silver plated copper and is typically referred to as the “plate.” The copper is generally 0.4 mm thick and the silver layer approximately 0.01 mm. There were several ways to plate the copper with silver. The most common was a process called Sheffield plating in which copper and silver plate were placed in contact, heated to just under the melting point of silver, cooled, and then repeatedly run through a rolling mill, slowing closing the gap between the rollers until the plate was the desired thickness. The plates increased in length during this process and were cut down to standard sizes. Another way, which became commercially popular in the mid-1850s, was to electroplate the silver onto the copper plate. Electroplating uses an electro-chemical reaction in which silver is deposited onto the surface of the copper plate through the use of a galvanic battery. There were several ways to do this, but one common way was to immerse the copper plate with a silver anode into a saturated solution of silver chloride or silver nitrate and potassium cyanide. The anode was hooked to a galvanic battery which produced an electric current causing the silver in the bath to chemically deposit onto the copper plate. Electroplating was also used by practitioners to add more silver to the plate allowing it to be more finely polished in a process also known as galvanizing or resilvering. The French silver industry required silver to bear a hallmark and maker’s mark. The hallmark includes numbers, words, initials or images that denote the quality or the proportions of silver to copper. The word “double” identifies the silver as plated and the scale symbol means that it was electroplated. The maker’s mark is a design including words, initials, or images indicating the manufacturer of the plate. US manufacturers followed this practice as well to indicate that their plates were as good as French plates. 
Image: Color/Tone, Quality 
The image is composed of very small, nanoparticles of silver-mercury amalgam and gold resting on the surface of the silver plate. How exactly the image is formed and where and how the gold rests in relation to the image particles is not universally agreed on but it appears that the gold is deposited on both the image particles and the silver substrate. The image is a direct positive, meaning the image particles are in the highlights rather than the shadows. Due to the reflective nature of the silver substrate and the way in which the image particles scatter light, the image appears both as a positive and a negative depending on the viewing angle. The daguerreotype is capable producing an image with extremely high resolution, creating very detailed, almost holographic images. The image is typically monochromatic (black and white) with some exceptions. Over exposure of the highlights causes solarization, resulting in a blue tone in the highlights. Images may also be hand colored. 

Chemical deterioration impacts the overall appearance of the daguerreotype. The major form of chemical deterioration is tarnish, or corrosion, which is composed of extremely thin films of silver oxide and silver sulfide and appears as interference colors ranging from brown to blue to salmon. Edge tarnish usually forms from the outside-in due to oxidizing gases and pollutants entering the package, and primarily consist of silver sulfide. Mat tarnish, forming where the mat contacts the plate, is typically composed of silver oxide.

Exfoliation may occur due to flaws in the manufacturing of the plate or, according to some recent studies, be caused during the gilding step if the duration of the plate gilding is extended for too long. 
Formats/Mounting
The surface of the daguerreotype, gilded or ungilded, is extremely delicate and highly susceptible to abrasions and deterioration from environmental pollutants. Therefore daguerreotypes were nearly always housed in a protective case or frame. American and British daguerreotypes are commonly housed in small, hinged cases similar to those already used to house painted miniatures. The daguerreotype package includes the daguerreotype plate, a brass mat, and cover glass bound together with paper tape. A flexible, decorative brass preserver was bent over the edge to cover the tape and the package fit tightly into the case. The cases were of wood covered in molded leather or paper with a silk or velvet pad in the interior. Thermoplastic “Union” cases were produced between 1855 and 1865. Daguerreotypes made in Continental Europe were housed in a passe-partout, a style of framing usually consisting of a paper mat or metal spacers, glass glazing, and a decorative frame which could be hung or propped on a table.

Plates came in standard sizes as follows:

American Plate Sizes
  •  Whole plate, 6 ½ x 8 ½ in.
  • Half plate, 4 ¼ x 5 ½ in.  
  • Quarter plate, 3 ¼ x 4 ¼ in.
  • Sixth plate, 2 ¾ x 3 ¼ in.
  • Ninth plate, 2 x 2 ½ in.
  • Sixteenth plate, 1 3/8 x 1 5/8 in.
  • Gem plate, 1 x 1 in.

European Plate Sizes
  • Whole plate, 16.2 x 21.6 cm
  • Half plate, 10.8 x 16.2 cm
  • Third plate, 7.2 x 16.2 cm
  • Quarter plate, 8.1 x 10.8 cm
  • Sixth plate, 7.2 x 8.1 cm
  • Eighth plate, 5.4 x 8.1 cm
  • Ninth plate, 5.4 x 7.2 cm
  • Sixteenth plate, 4.0 x 5.4 cm 
Finishing Techniques
Daguerreotypes could be hand colored using several methods. Finely ground pigment could be combined with a medium such as gum arabic, starch, or gelatin and applied to the plate with a brush. A transparent varnish or adhesive may be applied to the plate and then ground pigments brush applied or dusted on. Dry, ground pigment could be brush applied to the plate and then set by gently breathing on the plate or by applying slight heat. Many daguerreotypes have subtly applied coloring to enhance the color of the face, clothing or jewelry. Jewelry could be enhanced by mechanically picking the plate with a needle or with gold paint. Less common, though sometimes made, are plates that are completely hand colored, obscuring the image. 
Information Written or Printed on Object 
Occasionally, information may be written on a piece of paper and placed inside the case along with the plate. Though rare, objects such as other photographs or locks of hair can sometimes be found inside the case as well.